| DOI | Trouver le DOI : https://doi.org/10.1021/nn4034234 |
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| Auteur | Rechercher : Luber, Erik J.1; Rechercher : Mobarok, Md Hosnay1; Rechercher : Buriak, Jillian M.1 |
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| Affiliation | - Conseil national de recherches du Canada. Technologies de sécurité et de rupture
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| Format | Texte, Article |
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| Sujet | Core-shell; earth-abundant; Photovoltaics; Semiconductor nanocrystals; Solution-processed; Zinc phosphide; Heterojunctions; Molybdenum oxide; Nanocrystals; Nanoparticles; Photoelectron spectroscopy; Photoelectrons; Quantum confinement; Synthesis (chemical); Thin films; Transmission electron microscopy; X ray diffraction; X ray photoelectron spectroscopy; Zinc |
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| Résumé | Zinc phosphide (Zn3P2) is a promising earth-abundant material for thin film photovoltaic applications, due to strong optical absorption and near ideal band gap. In this work, crystalline zinc phosphide nanoparticles are synthesized using dimethylzinc and tri-n-octylphosphine as precursors. Transmission electron microscopy and X-ray diffraction data show that these nanoparticles have an average diameter of ∼8 nm and adopt the crystalline structure of tetragonal α-Zn3P2. The optical band gap is found to increase by 0.5 eV relative to bulk Zn 3P2, while there is an asymmetric shift in the conduction and valence band levels. Utilizing layer-by-layer deposition of Zn 3P2 nanoparticle films, heterojunction devices consisting of ITO/ZnO/Zn3P2/MoO3/Ag are fabricated and tested for photovoltaic performance. The devices are found to exhibit excellent rectification behavior (rectification ratio of 600) and strong photosensitivity (on/off ratio of ∼10²). X-ray photoelectron spectroscopy and ultraviolet photoemission spectroscopy analyses reveal the presence of a thin 1.5 nm phosphorus shell passivating the surface of the Zn3P 2 nanoparticles. This shell is believed to form during the nanoparticle synthesis. |
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| Date de publication | 2013-08-12 |
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| Dans | |
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| Langue | anglais |
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| Publications évaluées par des pairs | Oui |
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| Numéro NPARC | 21270521 |
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| Exporter la notice | Exporter en format RIS |
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| Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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| Identificateur de l’enregistrement | ae7f8f26-1d83-4169-9e87-cebfd4b01348 |
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| Enregistrement créé | 2014-02-14 |
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| Enregistrement modifié | 2020-04-22 |
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