Asymptotic energy levels of a rigid asymmetric top

DOI	Trouver le DOI : https://doi.org/10.1080/00268970701241672
Auteur	Rechercher : Watson, James K. G.¹
Affiliation	Conseil national de recherches du Canada. Institut Steacie des sciences moléculaires du CNRC
Format	Texte, Article
Résumé	The spectra of larger molecules are often observed to high rotational quantum numbers, and the asymptotic behaviour of the rotational energy levels is of interest. This paper is mainly concerned with the lowest-energy levels for high values of J. These tend to occur in oblate-type doublets, for which E. K. Gora gave an energy-level formula in 1965 that seems to be little known among pure rotational spectroscopists. In particular, the mean energies and splittings of these doublets are discussed and a new derivation of Gora's formula is described.
Date de publication	2007-05-16
Dans	Molecular Physics 105, nº 5 (16 mai 2007) : 679–.
Langue	anglais
Numéro NPARC	12328978
Exporter la notice	Exporter en format RIS
Signaler une correction	Signaler une correction (s'ouvre dans un nouvel onglet)
Identificateur de l’enregistrement	b8970bbb-d941-4429-a0fc-e4c264d121b8
Enregistrement créé	2009-09-10
Enregistrement modifié	2020-05-10