The configuration of glycosidic linkages in oligosaccharides: VI. Degradation of 4-O-Methyl-D-Glucopyranuronosyl-aldobiuronic acids to 2-O-(4-O-methyl-D-glucopyranosyl)-gycerols

Par Conseil national de recherches du Canada

Téléchargement	Voir la version finale : The configuration of glycosidic linkages in oligosaccharides: VI. Degradation of 4-O-Methyl-D-Glucopyranuronosyl-aldobiuronic acids to 2-O-(4-O-methyl-D-glucopyranosyl)-gycerols (PDF, 371 Kio)
DOI	Trouver le DOI : https://doi.org/10.1139/v58-142
Auteur	Rechercher : Gorin, P. A. J.¹; Rechercher : Perlin, A. S.¹
Affiliation	Conseil national de recherches du Canada. Laboratoire régional des prairies
Format	Texte, Article
Résumé	The configurations of glycosidic linkages in 4-O-methyl-D-glucopyranuronosyl-aldobiuronic acids can be determined by conversion to the derived 2-O-D-glucopyranosyl-glycerol hexamethyl ether, which is compared, by its infrared spectrum and specific rotation, with the sirupy hexamethyl ethers synthesized from 2-O-α- and 2-O-β-D-glucopyranosyl-glycerol. Thus, the configuration of 2-O-(4-O-methyl-D-glucopyranuronosyl)-D-xylose was shown to be α, since it was degraded to 2-O-α-D-glucopyranosyl-glycerol hexamethyl ether. The configuration of 4-O-(4-O-methyl-D-glucopyranuronosyl)-D-galactose was correlated with that of the former aldobiuronic acid, since both gave crystalline 2-O-α-(4-O-methyl-D-glucopyranosyl)-glycerol penta-p-nitrobenzoate.
Date de publication	1958-06-01
Maison d’édition	Canadian Science Publishing
Dans	Canadian Journal of Chemistry 36, nº 6 (1 juin 1958) : 999–1003.
Langue	anglais
Publications évaluées par des pairs	Oui
Identificateur	NRCC-4730
Exporter la notice	Exporter en format RIS
Signaler une correction	Signaler une correction (s'ouvre dans un nouvel onglet)
Identificateur de l’enregistrement	bb141e06-2d61-417c-b5ac-61dbaccfe998
Enregistrement créé	2023-09-14
Enregistrement modifié	2023-09-14

Date de modification :: 2024-07-05