| DOI | Trouver le DOI : https://doi.org/10.1002/chem.200800762 |
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| Auteur | Rechercher : Wang, Yishan; Rechercher : Zou, Shan1; Rechercher : Kim, Kyoung Taek; Rechercher : Manners, Ian; Rechercher : Winnik, Mitchell A. |
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| Affiliation | - Conseil national de recherches du Canada. Institut Steacie des sciences moléculaires du CNRC
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| Format | Texte, Article |
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| Sujet | block copolymers; micelles; polyferrocenylsilane; polypeptides; rod-coil |
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| Résumé | A new type of metallopolymer‐polypeptide block copolymer poly(ferrocenyldimethylsilane)‐b‐poly (ε‐benzyloxycarbonyl‐l‐lysine) was synthesized by ring‐opening polymerization of ε‐benzyloxycarbonyl‐l‐lysine N‐carboxyanhydride initiated by using a primary amino‐terminated poly(ferrocenyldimethylsilane). Studies on the self‐organization behavior of this polypeptide block copolymer in both the bulk state and in solution were performed. In the bulk state, a cylindrical‐in‐lamellar structure was observed in a compositionally asymmetric sample. Rod‐like micelles with a polyferrocenylsilane core formed in a polypeptide‐selective solvent alone or in the presence of a common solvent. Significantly, an additional small quantity of the common solvent assisted the formation of longer micelles and micelles with better shape‐regularity. This is attributed to a decrease in the number of nucleation events and PFS core reorganization effects. |
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| Date de publication | 2008-09-26 |
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| Maison d’édition | Wiley |
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| Dans | |
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| Langue | anglais |
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| Publications évaluées par des pairs | Oui |
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| Exporter la notice | Exporter en format RIS |
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| Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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| Identificateur de l’enregistrement | c1bab22f-22b4-4cbc-a011-602dac1c2f89 |
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| Enregistrement créé | 2019-04-25 |
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| Enregistrement modifié | 2020-04-15 |
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