DOI | Trouver le DOI : https://doi.org/10.1080/15435070903364764 |
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Auteur | Rechercher : Min, K.1; Rechercher : Sun, C. W.1; Rechercher : Qu, W.1; Rechercher : Zhang, X. G.; Rechercher : Yick, S.1; Rechercher : Robertson, M.1; Rechercher : Decès-Petit, C.; Rechercher : Hui, R.1 |
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Affiliation | - Conseil national de recherches du Canada. Institut d'innovation en piles à combustible du CNRC
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Format | Texte, Article |
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Sujet | solid oxide fuel cells; cathode; interconnect; chromium poisoning; low temperature |
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Résumé | Rapid performance degradations of solid oxide fuel cells were observed when the chromium-forming metallic alloys were used as interconnects. The formation of strontium chromium oxide (SrCrO4) on the surface of Sr-doped perovskite cathode was believed to be one of the main causes for the cell degradation. This chromium-poisoning effect was not mitigated when the operating temperature was lowered to 600°C. The SrCrO4 that formed mainly on the cathode surface was found in both La0.6Sr0.4Co0.2Fe0.8O3−δ (LSCF) and Sm0.5Sr0.5CoO3 (SSCo) cathode, suggesting that all strontium-containing cathodes may develop low conductive chromite oxide compounds. However, this chromium-poisoning effect can be effectively mitigated by coating a protective layer on the surface of the interconnect. |
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Date de publication | 2009-12-09 |
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Maison d’édition | Taylor & Francis |
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Dans | |
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Langue | anglais |
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Publications évaluées par des pairs | Oui |
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Numéro NPARC | 23004797 |
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Exporter la notice | Exporter en format RIS |
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Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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Identificateur de l’enregistrement | d01abc5b-8d8b-4eb8-baed-35de3109dea8 |
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Enregistrement créé | 2018-12-20 |
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Enregistrement modifié | 2020-04-16 |
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