Reactions of the cumyloxyl and benzyloxyl radicals with tertiary amides. hydrogen abstraction selectivity and the role of specific substrate-radical hydrogen bonding
Reactions of the cumyloxyl and benzyloxyl radicals with tertiary amides. hydrogen abstraction selectivity and the role of specific substrate-radical hydrogen bonding
DOI | Trouver le DOI : https://doi.org/10.1021/jo400535u |
---|---|
Auteur | Rechercher : ; Rechercher : ; Rechercher : 1; Rechercher : |
Affiliation |
|
Format | Texte, Article |
Sujet | Hydrogen abstraction reaction; Hydrogen bond interaction; Intramolecular hydrogen; N ,N-Dimethylacetamide; N ,N-Dimethylformamide; Rate-limiting formation; Theoretical investigations; Time-resolved kinetic study; Amides; Functional groups; Hydrogen bonds; Organic solvents; Substrates; Abstracting; acetic acid derivative; aliphatic amine; amide; benzyloxyl radical; carbon; cumyloxyl radical; dimethyl sulfoxide; hydrogen; hydroxyl radical; n,n dimethylacetamide; n,n dimethylformamide; oxygen; tertiary amine; unclassified drug; calculation; chemical reaction kinetics; chemical structure; density functional theory; dissociation constant; enzyme specificity; hydrogen bond; mathematical computing; molecular interaction; phase transition; stereochemistry |
Résumé | |
Date de publication | 2013 |
Dans | |
Langue | anglais |
Publications évaluées par des pairs | Oui |
Numéro NPARC | 21269778 |
Exporter la notice | Exporter en format RIS |
Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
Identificateur de l’enregistrement | e9fe8d3f-7635-41cb-921e-9cd360c3570c |
Enregistrement créé | 2013-12-13 |
Enregistrement modifié | 2020-04-22 |
- Date de modification :