Kinetic applications of electron paramagnetic resonance spectroscopy. XXIV. Neophyl rearrangements

DOI	Resolve DOI: https://doi.org/10.1021/ja00421a028
Author	Search for: Maillard, B.¹ ; Search for: Ingold, K. U.¹
Name affiliation	National Research Council Canada
Format	Text
Type	Article
Journal title	Journal of the American Chemical Society
ISSN	0002-7863
Volume	98
Issue	5
Pages	1224–1226; # of pages: 3
Abstract	The rate constants for isomerization of 2-aryl-2-methylpropyl-1 to 1-aryl-2-methylpropyl-2 radicals have been measured by EPR spectroscopy over a range of temperatures. The radicals were derived by hydrogen abstraction from the following compounds: tert-butylbenzene, 1,3-di-tert-butylbenzene, 4-tert-butylpyridine, 2,6-di-tert-butylpyridine, and 2-tert-butylnaphthalene. The rates of isomerization of the radicals derived from the two pyridines and the naphthalene are significantly faster than the rates of isomerization of the radicals from the two benzenes.
Publication date	1976
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Language	English
Peer reviewed	Yes
NPARC number	21276700
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Record identifier	2e349d17-0649-4ebe-88f7-b0986c9830ee
Record created	2015-10-13
Record modified	2016-05-09