| Download | - View final version: D-APIOSE (PDF, 445 KiB)
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| DOI | Resolve DOI: https://doi.org/10.1139/v58-068 |
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| Author | Search for: Gorin, P. A. J.1; Search for: Perlin, A. S.1 |
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| Affiliation | - National Research Council of Canada. Prairie Regional Laboratory
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| Format | Text, Article |
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| Abstract | Naturally-occurring apiose is shown by synthesis to be the D-isomer in the open-chain form. In this synthesis 3-O-benzyl-D-fructose is cyanohydrated and the resulting heptonic lactones are reduced to 3-O-benzyl-2-C-(hydroxymethyl)-D-arabo-hexitol. The latter is oxidized with lead tetraacetate affording 2-O-benzyl-3-C-(hydroxymethyl)-D-glycero-tetrose which, on debenzylation, gives 3-C-(hydroxymethyl)-D-glycero-tetrose (D-apiose). |
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| Publication date | 1958-03-01 |
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| Publisher | Canadian Science Publisher |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| Identifier | NRCC-4612 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 765f6334-befa-43f0-b43d-36c36336a10e |
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| Record created | 2023-09-14 |
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| Record modified | 2023-09-14 |
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