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Time-resolved photoelectron angular distributions: concepts, applications, and directions

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1146/annurev.physchem.53.082101.130051
AuthorSearch for: 1
Affiliation
  1. National Research Council Canada. NRC Steacie Institute for Molecular Sciences
FormatText, Article
Subjectfemtochemistry; angle-resolved photoionization; photoelectron imaging; radiationless transitions; time-dependent alignment
Abstract
The use of photoelectron angular distributions (PADs) as a probe in short-pulse, pump-probe scenarios is reviewed. We focus on concepts, on the insight that can be gained through theoretical analysis, on applications, and on future opportunities. Time-resolved PADs are sensitive to both the time-evolving rotational composition of wavepackets and their time-evolving electronic symmetry. The former feature renders this observable a potential probe of molecular structure, intensity effects, and rotational perturbations. The latter feature renders the PAD a potential probe of radiationless transitions.
Publication date
In
  • Annual Review of Physical Chemistry 53 (28 November 2003): 41–65.
NPARC number12327058
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Record identifier8991736b-92f2-48d1-81d0-3c5ffe893be9
Record created2009-09-10
Record modified2020-04-02
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