| DOI | Resolve DOI: https://doi.org/10.1080/00268977200100841 |
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| Author | Search for: Kiefer, W.1; Search for: Bernstein, H. J.1 |
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| Affiliation | - National Research Council of Canada
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| Format | Text, Article |
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| Abstract | Resonance Raman spectra have been obtained from the MnO4- and CrO4 2- ions in aqueous solutions and as solid. High intensity overtone progressions of the totally symmetric vibration v 1 were observed, allowing estimates of the anharmonicity constants and harmonic frequencies to be made for the v 1 breathing mode. Relative intensities have been measured in the resonance case and correlated with the absorption spectra. Also preresonance intensity data for CrO4 2- have been determined and discussed in terms of an existing theory. The overtone progression of v 1 shows a large increase in half-bandwidth with increasing vibrational quantum number. |
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| Publication date | 1972-05 |
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| Publisher | Taylor & Francis |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NRC number | NRCC 12668 |
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| NPARC number | 23002988 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 8b9b35b1-d609-46aa-b153-1a14164eb871 |
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| Record created | 2018-04-04 |
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| Record modified | 2020-03-13 |
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