The resonance Raman effect of the permanganate and chromate ions

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1080/00268977200100841
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Name affiliation
  1. National Research Council Canada
FormatText
TypeArticle
Journal titleMolecular Physics
ISSN0026-8976
1362-3028
Volume23
Issue5
Pages835–851
Abstract
Resonance Raman spectra have been obtained from the MnO4 - and CrO4 2- ions in aqueous solutions and as solid. High intensity overtone progressions of the totally symmetric vibration v 1 were observed, allowing estimates of the anharmonicity constants and harmonic frequencies to be made for the v 1 breathing mode. Relative intensities have been measured in the resonance case and correlated with the absorption spectra. Also preresonance intensity data for CrO4 2- have been determined and discussed in terms of an existing theory. The overtone progression of v 1 shows a large increase in half-bandwidth with increasing vibrational quantum number.
Publication date
PublisherTaylor & Francis
LanguageEnglish
Peer reviewedYes
NRC numberNRCC 12668
NPARC number23002988
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Record created2018-04-04
Record modified2018-04-04
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