The resonance Raman effect of the permanganate and chromate ions

DOI	Resolve DOI: https://doi.org/10.1080/00268977200100841
Author	Search for: Kiefer, W.¹; Search for: Bernstein, H. J.¹
Name affiliation	National Research Council of Canada
Format	Text, Article
Journal title	Molecular Physics
ISSN	0026-8976 1362-3028
Volume	23
Issue	5
Pages	835–851
Abstract	Resonance Raman spectra have been obtained from the MnO4- and CrO4 2- ions in aqueous solutions and as solid. High intensity overtone progressions of the totally symmetric vibration v 1 were observed, allowing estimates of the anharmonicity constants and harmonic frequencies to be made for the v 1 breathing mode. Relative intensities have been measured in the resonance case and correlated with the absorption spectra. Also preresonance intensity data for CrO4 2- have been determined and discussed in terms of an existing theory. The overtone progression of v 1 shows a large increase in half-bandwidth with increasing vibrational quantum number.
Publication date	1972-05
Publisher	Taylor & Francis
Language	English
Peer reviewed	Yes
NRC number	NRCC 12668
NPARC number	23002988
Export citation	Export as RIS
Report a correction	Report a correction
Record identifier	8b9b35b1-d609-46aa-b153-1a14164eb871
Record created	2018-04-04
Record modified	2020-03-13