| DOI | Trouver le DOI : https://doi.org/10.1080/00268977200100841 |
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| Auteur | Rechercher : Kiefer, W.1; Rechercher : Bernstein, H. J.1 |
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| Affiliation | - Conseil national de recherches du Canada
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| Format | Texte, Article |
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| Résumé | Resonance Raman spectra have been obtained from the MnO4- and CrO4 2- ions in aqueous solutions and as solid. High intensity overtone progressions of the totally symmetric vibration v 1 were observed, allowing estimates of the anharmonicity constants and harmonic frequencies to be made for the v 1 breathing mode. Relative intensities have been measured in the resonance case and correlated with the absorption spectra. Also preresonance intensity data for CrO4 2- have been determined and discussed in terms of an existing theory. The overtone progression of v 1 shows a large increase in half-bandwidth with increasing vibrational quantum number. |
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| Date de publication | 1972-05 |
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| Maison d’édition | Taylor & Francis |
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| Dans | |
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| Langue | anglais |
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| Publications évaluées par des pairs | Oui |
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| Numéro du CNRC | NRCC 12668 |
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| Numéro NPARC | 23002988 |
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| Exporter la notice | Exporter en format RIS |
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| Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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| Identificateur de l’enregistrement | 8b9b35b1-d609-46aa-b153-1a14164eb871 |
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| Enregistrement créé | 2018-04-04 |
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| Enregistrement modifié | 2020-03-13 |
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