| DOI | Trouver le DOI : https://doi.org/10.1002/anie.200804560 |
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| Auteur | Rechercher : Vaidya, V.; Rechercher : Ingold, K. U.1; Rechercher : Pratt, D.A. |
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| Affiliation | - Conseil national de recherches du Canada
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| Format | Texte, Article |
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| Sujet | Acids; Chemical properties; Chemical reactions; Electron transitions; Metabolites; Oxidation; Proton transfer; Protons; Sulfur; Allicin; Antioxidants; Garlic; Lipid peroxidation; Peroxyl radicals; Free radical reactions; antioxidant; hydrogen peroxide; sulfenic acid derivative; chemical structure; chemistry; garlic; temperature; Antioxidants; Garlic; Hydrogen Peroxide; Molecular Structure; Sulfenic Acids; Temperature |
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| Résumé | (Chemical Equation Presented) The medicinal properties of garlic, thought to derive at least in part from the antioxidant activity of its sulfur-containing secondary metabolites, have been recognized for hundreds of years. The ability of garlic to scavenge peroxyl radicals can be accounted for in terms of the action of transient sulfenic acids, which are predicted to react by diffusion-controlled five-center proton-coupled electron transfer (see scheme and transition state). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA. |
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| Date de publication | 2009 |
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| Dans | |
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| Langue | anglais |
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| Publications évaluées par des pairs | Oui |
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| Numéro NPARC | 21276662 |
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| Exporter la notice | Exporter en format RIS |
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| Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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| Identificateur de l’enregistrement | 4ae0d571-6a4c-458a-8179-abdde9ae378b |
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| Enregistrement créé | 2015-10-13 |
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| Enregistrement modifié | 2020-04-16 |
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